Effect of the physico-chemical properties of vanadia/praseodymia on cyclohexanol decomposition

被引:0
|
作者
Thankappan Radhika
Sankaran Sugunan
机构
[1] Cochin University of Science and Technology,Department of Applied Chemistry
来源
Reaction Kinetics and Catalysis Letters | 2007年 / 90卷
关键词
Supported vanadia; praseodymia; cyclohexanol decomposition;
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学科分类号
摘要
Vanadia supported on praseodymia (2, 6 and 10 wt.% V2O5) were prepared by wet impregnation and characterized by energy dispersive X-ray analysis (EDAX), X-ray diffraction (XRD), TGA/DTA and BET surface area measurements. Decomposition of cyclohexanol was conducted over these catalysts in the vapor phase. Acidity of the catalysts was measured by temperature programmed desorption using ammonia as a probe molecule. The structural and acidic properties were correlated to the total conversion and cyclohexene selectivity.
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页码:243 / 250
页数:7
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