Effect of Acid Site Localization in Sulfonic Resin Amberlyst 15 on its Catalytic Properties in Ethyl tert-butyl Ether Synthesis

被引：0
|
作者：
Yu. N. Kochkin
N. V. Vlasenko
P. E. Strizhak
机构：
[1] National Academy of Sciences of Ukraine,L. V. Pysarzhevsky Institute of Physical Chemistry
来源：
Theoretical and Experimental Chemistry | 2017年 / 53卷
关键词：
sulfonic resins; ethyl tert-butyl ether; ethanol; isobutylene; Amberlyst 15; localization; acid sites;
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暂无
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学科分类号：
摘要：
The role of the localization of acid sites in macroporous sulfonic resin Amberlyst 15 in the synthesis of ethyl tert-butyl ether was investigated. By partial blockage of the acid sites by Na+ cations it was established that internal acid sites are primarily active in the reaction while a side reaction with the formation of tert-butanol takes place at the external acid sites.
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页码：138 / 142
页数：4
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