On the use of metal-organic frameworks for the extraction of organic compounds from environmental samples

The determination of trace metals and organic contaminants in environmental samples, such as water, air, soil, and sediment, is until today a challenging process for the analytical chemistry. Metal-organic frameworks (MOFs) are novel porous nanomaterials that are composed of metal ions and an organic connector. These materials are gaining more and more attention due to their superior characteristics, such as high surface area, tunable pore size, mechanical and thermal stability, luminosity, and charge transfer ability between metals and ligands. Among the various applications of MOFs are gas storage, separation, catalysis, and drug delivery. Recently, MOFs have been successfully introduced in the field of sample preparation for analytical chemistry and they have been used for sample pretreatment of various matrices. This review focuses on the applications of MOFs as novel adsorbents for the extraction of organic compounds from environmental samples.