Inclusion of amides by a fluorenyl diol host

被引：0
|
作者：
Elise J. C. de Vries
Luigi R. Nassimbeni
Edwin Weber
机构：
[1] University of Cape Town,Department of Chemistry
[2] Technische Universität Bergakademie Freiberg,Institut für Organische Chemie
来源：
Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2009年 / 63卷
关键词：
Inclusion complex; Thermal analysis; Lattice energies;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structure of the host compound 1,4-bis(9-hydroxy-9-fluorenyl)benzene as well as the structures of the inclusion complexes with four amides, dimethylformamide (DMF), dimethylacetamide (DMA), tetramethylurea (TMU) and hexamethylphosphoramide (HMPA) have been elucidated. Each structure crystallised in a centrosymmetric space group with Z = 2 and a host to guest ratio of 1:1 or 1:2, as determined by thermogravimetric analysis. Lattice energies have been calculated by atom-atom potential methods and these results were compared to the thermal stabilities observed.
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页码：203 / 210
页数：7
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