Optimization of solar irradiated Fenton treatment of pesticide chlorpyrifos wastewater by response surface methodology

被引:0
作者
Affam Chioma Augustine
Malay Chaudhuri
Kimberly Hetrick
机构
[1] University College of Technology Sarawak,Civil Engineering Department, School of Engineering and Technology
[2] Universiti Teknologi PETRONAS,Department of Civil Engineering
[3] Lehigh University,Department of Civil Engineering
[4] United States of America,undefined
来源
Environmental Earth Sciences | 2016年 / 75卷
关键词
Solar; Fenton; Chlorpyrifos; Response surface methodology (RSM);
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摘要
The study examined solar irradiation for enhancement of Fenton treatment of pesticide chlorpyrifos wastewater. Optimization of the process was achieved by employing the central composite design (CCD). Total organic removal (TOC) removal of 89.2 % was obtained under the optimized conditions (pH 3, H2O2/COD 2.25 and H2O2/Fe2+ 10 molar ratios and 60 min reaction time). The improvement of biodegradability (BOD5/COD ratio) index from 0 to 0.41 obviously indicated that biological treatment could be applied after pretreatment for complete treatment of the wastewater. The experimental results and model prediction had an error less than 5 % owing to the close data obtained. Solar irradiated Fenton treatment is effective for the pretreatment of pesticide chlorpyrifos wastewater before biological treatment maybe applied.
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