Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O

被引：0
|
作者：
P. A. Abramov
M. N. Sokolov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National Research State University,undefined
来源：
Journal of Structural Chemistry | 2017年 / 58卷
关键词：
hexaniobate; sodium; X-ray diffraction analysis;
D O I：
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中图分类号：
学科分类号：
摘要：
The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.
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页码：1411 / 1417
页数：6
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