Synthesis of fullerene Γ-lactones by free radical reaction of C60 with ketones promoted by compounds of transition metals Cr(VI), Ce(IV)

被引:0
|
作者
R. G. Bulgakov
Z. S. Kinzyabaeva
机构
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词
Fullerene; Free Radical Reaction; Cerium Ammonium Nitrate; Fullerene Cage; Semipreparative HPLC;
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学科分类号
摘要
One-step synthesis was developed for fullerene Γ-lactones by the reaction of C60 with aromatic and aliphatic ketones in the presence of transition metal compounds CrO3, K2Cr2O7, (NH4)2Ce(NO3)6 ·6H2O.
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页码:1189 / 1193
页数:4
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