Electrochemical amination of anisole in 4–6 M solutions of H2SO4 and acetonitrile

被引：0
|
作者：
Yu. A. Lisitsyn
A. V. Sukhov
机构：
[1] Kazan (Volga Region) Federal University,Butlerov Chemical Institute
来源：
Russian Journal of Electrochemistry | 2013年 / 49卷
关键词：
cathode; Ti(IV)/Ti(III) mediator system; hydroxylamine; amino radical cation; aromatic radical cation substitution;
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摘要：
Indirect cathode amination of anisole with Ti(IV)/Ti(III) and NH2OH in media containing 4 or 6 M H2SO4, CH3CN, and H2O (in small amounts) was studied. Para- and ortho-anisidines were the major products of radical cation substitution at 15–45°C. The total yield of monoamino compounds based on the source of amino radicals (with its full conversion) may be up to 84% in these conditions.
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页码：91 / 95
页数：4
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