A Copper(II)-Lanthanoid(III)-Glycine Complex with High-Nuclearity, [{La6Cu26gly18(μ3-OH)30(H2O)24 (ClO4)}(ClO4)21·26H2O]n

被引：3
作者：
Shengmin Hu
Jingcao Dai
Xintao Wu
Liming Wu
Chuanpeng Cui
Zhiyong Fu
Maochun Hong
Yucang Liang
机构：
[1] Chinese Academy of Sciences,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter
来源：
Journal of Cluster Science | 2002年 / 13卷
关键词：
copper(II); lanthanide(III); amino acids; high nuclearity; 1-D chain;
D O I：
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中图分类号：
学科分类号：
摘要：
The 1-D complex with high-nuclearity [{La6Cu26gly18(μ3-OH)30(H2O)24(ClO4)} (ClO4)21·26H2O]n was synthesized and characterized by X-ray diffraction analysis. The inner core of the basic unit is an octahedron with La3+ ions at its vertexes and Cu2+ ions at the meddles of the twelve edges. Two additional Cu2+ ions are connected to each La3+ vertex to form a [La6Cu24] unit, and adjacent units are interconnected by a pair [Cu(gly)2] bridges to give a polymeric chain structure.
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页码：33 / 41
页数：8
相关论文
共 79 条
  • [1] Bencini A.(1985)undefined J. Amer. Chem. Soc. 107 8128-undefined
  • [2] Benelli C.(1990)undefined Inorg. Chem. 29 1750-undefined
  • [3] Caneschi A.(2000)undefined Angew. Chem. Int. 39 3304-undefined
  • [4] Carlin R. L.(1995)undefined J. Amer. Chem. Soc. 117 9600-undefined
  • [5] Dei A.(1998)undefined Inorg. Chem. 37 6186-undefined
  • [6] Gatteschi D.(1994)undefined Phys. Rev. B 49 3235-undefined
  • [7] Benelli C.(1993)undefined J. Amer. Chem. Soc. 115 1822-undefined
  • [8] Caneschi A.(1997)undefined Inorg. Chem. 36 930-undefined
  • [9] Gatteschi D.(1998)undefined Inorg. Chem. 37 2443-undefined
  • [10] Guilou O.(1986)undefined Inorg. Chem. 25 572-undefined
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