Molecular and supramolecular structures in biological fluids and their homochiral models

被引:0
作者
S. V. Stovbun
A. A. Skoblin
机构
[1] Russian Academy of Sciences,Semenov Institute of Chemical Physics
来源
Moscow University Physics Bulletin | 2012年 / 67卷
关键词
dynamic light scattering; IR spectroscopy; chirality; molecular associations; average field;
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学科分类号
摘要
The structures of homochiral solutions that simulate biological fluids were studied. Dynamic light scattering revealed three structural groups in them, viz., (1–10) nm (molecular associations); 10 μm (strings), and 1 μm (isometric grains). IR spectroscopy and chirotropical measurements confirmed the presence of associations. We considered a statistical model for the formation of molecular association and the formation of strings in the average field of associations.
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页码:274 / 277
页数:3
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