Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescent Properties

被引：0
作者：
Dong-Bin Dang
Guang-Shui Zheng
Yan Bai
机构：
[1] Henan University,Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering
来源：
Journal of Inorganic and Organometallic Polymers and Materials | 2010年 / 20卷
关键词：
Silver(I); Coordination polymer; Schiff base; Crystal structure; Luminescence;
D O I：
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中图分类号：
学科分类号：
摘要：
A new Ag(I) coordination polymer [AgL(NO3)]n1 (L = 4-benzoylpyridine hydrazone) has been synthesized and characterized by IR, UV, elemental analysis, thermogravimetry and X-ray crystallography. Ag(I)-atom has a seesaw environment with a set of donors from three N-atoms of three ligands and one O-atom from one NO3− anion. Each ligand is bonded to three silver centers and each silver atom is coordinated by three ligands thereby generating two types of bimetallic metallocyclic unit to form a 1D chain. The 1D chains interact each other giving further rise to a 3D supramolecular network through multiform intermolecular hydrogen bonds. The luminescent properties of the polymer 1 at room temperature were investigated.
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页码：356 / 360
页数：4
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