Cobalt hexacyanoferrate-modified electrode for amperometric assay of hydrazine

被引:0
|
作者
Ravi Shankaran D. [1 ]
Sriman Narayanan S. [1 ]
机构
[1] Department of Analytical Chemistry, University of Madras
关键词
Oxidation; Physical Chemistry; Graphite; Cobalt; Detection Limit;
D O I
10.1023/A:1020241011841
中图分类号
学科分类号
摘要
A graphite electrode modified with cobalt hexacyanoferrate by mechanical immobilization was used for amperometric determination of hydrazine. The modified electrode exhibits good catalytic activity for the oxidation of hydrazine at a reduced overpotential with remarkable sensitivity. The modified electrode showed a linear response for hydrazine in the concentration range of 2.0 × 10-5 to 2.8 × 10-4 M. The detection limit was 9.8 × 10-6 M (S/N = 3). The proposed modified electrode was simple, sensitive, rapid, stable and promising.
引用
收藏
页码:987 / 991
页数:4
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