The thermodynamic characteristics of complex formation of Cd2+ with N,N-Bis(carboxymethyl)aspartic acid in aqueous solutions at 298.15 K

被引:0
|
作者
A. I. Lytkin
N. V. Chernyavskaya
V. E. Litvinenko
机构
[1] Ivanovo State University of Chemical Technology,
[2] Kostroma State University,undefined
来源
Russian Journal of Physical Chemistry A | 2011年 / 85卷
关键词
complex formation; thermodynamic characteristics; potentiometric titration;
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摘要
The equilibrium constants and heats of formation of complexes of N,N-bis(carboxymethyl)aspartic acid (H4Y) with Cd2+ ions at 298.15 K and ionic strengths of 0.2, 0.5, and 1.0 (KNO3) were determined by potentiometric titration and calorimetrically. The thermodynamic characteristics of formation of the CdY2− complex at fixed and zero ionic strength values were calculated. The values obtained were interpreted.
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页码:41 / 44
页数:3
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