Interaction of 2,2,6,6-tetramethylpiperidine-1-oxyl chloritewith alcohols

被引：0
|
作者：
I. M. Ganiev
E. S. Suvorkina
A. V. Igoshina
N. N. Kabal"nova
U. B. Imashev
G. A. Tolstikov
机构：
[1] Institute of Organic Chemistry,Ufa Research Center of the Russian Academy of Sciences
[2] Ufa State Petroleum Technical University,undefined
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
oxoammonium salt; 2,2,6,6-tetramethylpiperidine-1-oxyl chlorite; alcohols; rate constant;
D O I：
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摘要：
The kinetics of the oxidation of a series of alcohols (viz., ethanol, propan-2-ol, butan-1-ol, butan-2-ol, heptan-4-ol, decan-2-ol, propan-1,3-diol, butan-2,3-diol, cyclohexanol, benzyl alcohol, and borneol) with the oxoammonium salt 2,2,6,6-tetramethylpiperidine-1-oxyl chlorite in acetonitrile was studied by spectrophotometry. The products of oxidation of primary alcohols are the corresponding aldehydes and carboxylic acids, and the products of oxidation of secondary alcohols are ketones. The reaction rate is described by the second order equation. The rate constants and activation parameters were determined. The rate constant as a function of the alcohol nature is described by the one-parameter Taft equation.
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页码：982 / 985
页数：3
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