The role played by chain avalanches in the developed burning of hydrogen mixtures with oxygen and air at atmospheric pressure

被引:0
作者
V. V. Azatyan
Z. S. Andrianova
A. N. Ivanova
机构
[1] Russian Academy of Sciences,Institute of Structural Macrokinetics
[2] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源
Russian Journal of Physical Chemistry | 2006年 / 80卷
关键词
Combustion; Initial Reagent; Hydrogen Mixture; Chain Avalanche; Stoichiometric Hydrogen;
D O I
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学科分类号
摘要
The role of competition between reaction chain branching and termination at various burning stages accompanied by reaction mixture self-heating was studied by mathematically modeling combustion of hydrogen mixtures with air and oxygen at a 1 bar initial pressure. An algorithm was suggested that allowed chair branching to be switched off at various time moments during calculations with retaining all the other, including thermal, parameters. It was shown that the switching off of chain avalanches at any process stage resulted in virtually instantaneous burning termination no matter what level of reaction mixture self-heating was reached.
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页码:1044 / 1049
页数:5
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