Tetrahedral metallocages assembled from oligopyridine ligands and transition metal ions

被引：0
作者：
Leonard F. Lindoy
机构：
[1] The University of Sydney,School of Chemistry
来源：
Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2019年 / 94卷
关键词：
Tetrahedral cage; Metallosupramolecular; Self-assembly; Oligopyridine; Polypyridine; Post-synthetic modification;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The focus in the present mini-review is on the use of oligopyridines for the construction of tetrahedral M4L6 and M4L4 metallosupramolecular cages. These are typically synthesised by the reaction of C2-symmetric bis(bidentate) and C3-symmetric tris(bidentate) ligands with octahedral metal ions in the required stoichiometric ratio, resulting in the ligands occupying the edges (M4L6) or capping the faces (M4L4) of the respective tetrahedra. Where appropriate, host–guest binding and other properties of the cages are also presented.
引用
收藏
页码：121 / 131
页数：10
相关论文
共 425 条
[1]  
Glasson CRK(2008)Recent developments in the d-block metallo-supramolecular chemistry of polypyridyls Coord. Chem. Rev. 252 940-963
[2]  
Lindoy LF(2000)Bipyridine: the most widely used ligand. A review of molecules comprising at least two 2,2′-bipyridine units Chem. Rev. 100 3553-3590
[3]  
Meehan GV(2016)Quaterpyridines as scaffolds for functional metallosupramolecular materials Chem. Rev. 116 14620-14674
[4]  
Kaes C(2017)More hydra than Janus—non-classical coordination modes in complexes of oligopyridine ligands Coord. Chem. Rev. 350 84-104
[5]  
Katz A(2017)Coordination chemistry and application of mono- and oligopyridine-based macrocycles Coord. Chem. Rev. 350 320-339
[6]  
Hosseini MW(2013)The pyridyl group in ligand design for selective metal ion complexation and sensing Chem. Soc. Rev. 42 1415-1426
[7]  
Gorczynski A(2017)Multicavity metallosupramolecular architectures Chem. Asian. J. 12 2513-2523
[8]  
Harrowfield JM(2014)Stereochemical communication within tetrahedral capsules Chem. Lett. 43 256-263
[9]  
Patroniak V(2014)Stereochemistry in subcomponent self-assembly Acc. Chem. Res. 47 2063-2073
[10]  
Stefankiewicz AR(1988)Adamantoid chelate complexes.1. The first adamantoid alkaline-earth metal chelate complex—synthesis, structure, and reactivity Angew. Chem. Int. Ed. 27 851-853
12345678910