Solvation dynamics of a charge bubble in water

被引：0
作者：
Ranjit Biswas
Biman Bagchi
机构：
[1] Indian Institute of Science,Solid State and Structural Chemistry Unit
[2] Jawaharlal Nehru Centre for Advanced Scientific Research,undefined
来源：
Proceedings / Indian Academy of Sciences | 1997年 / 109卷 / 5期
关键词：
Solvation dynamics; ultrafast spectroscopy; ionic mobility; electron solvation;
D O I：
10.1007/BF02875977
中图分类号：
学科分类号：
摘要：
A microscopic theory is used to calculate the solvation-time correlation function, (S(t)), of a light, non-stationary charge bubble in water. The calculated correlation function is found to be similar to the energy-time correlation function of a solvated electron. The ionic mobility of a charge bubble of the size of the hydrated electron is also calculated. It is found that the mobility of the charge plays a very important role in its own solvation.
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页码：347 / 352
页数：5
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