N, F-Codoped Microporous Carbon Nanofibers as Efficient Metal-Free Electrocatalysts for ORR

被引:0
作者
Tianle Gong
Ruoyu Qi
Xundao Liu
Hong Li
Yongming Zhang
机构
[1] Shanghai Jiao Tong University,Shanghai Electrochemical Energy Devices Research Center, Shanghai Key Lab of Electrical Insulation and Thermal Aging, School of Chemistry and Chemical Engineering
[2] University of Jinan,School of Material Science and Engineering
来源
Nano-Micro Letters | 2019年 / 11卷
关键词
Metal-free catalyst; Oxygen reduction reaction; N, F-codoped; Carbon nanofiber; Polyvinylidene fluoride;
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摘要
A new and facile method to synthesize N, F-codoped microporous carbon nanofiber (N, F-MCF) electrocatalysts via electrospinning, hydrothermal process, and thermal treatment.Polyvinylidene fluoride is applied as a fluorine source in oxygen reduction reaction (ORR) catalysis for the first time in literature.N, F-MCFs exhibit distinguished electrocatalytic activity, stability, and methanol tolerance for ORR in alkaline media.
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  • [21] Paulikas AP(2018)Effective sulfur-doping in carbon by high-temperature molten salt bath and its electrocatalysis for oxygen reduction reaction Electrochem. Commun. 86 53-4937
  • [22] Greeley DJ(2012)Sulfur and nitrogen dual-doped mesoporous graphene electrocatalyst for oxygen reduction with synergistically enhanced performance Angew. Chem. Int. Ed. 124 11664-1729
  • [23] Shao M(2015)High-quality phosphorus-doped MOS Chem. Commun. 51 7903-387
  • [24] Peles A(2013) ultrathin nanosheets with amenable ORR catalytic activity Adv. Mater. 25 4932-142
  • [25] Shoemaker K(2013)Synthesis of phosphorus-doped graphene and its multifunctional applications for oxygen reduction reaction and lithium ion batteries ACS Catal. 3 1726-2169
  • [26] Li M(2014)Fluorine-doped carbon blacks: highly efficient metal-free electrocatalysts for oxygen reduction reaction Mater. Lett. 136 384-824
  • [27] Zhao Z(2015)Mesoporous fluorine-doped carbon as efficient cathode material for oxygen reduction reaction Carbon 93 130-9981
  • [28] Cheng T(2016)Nitrogen and fluorine co-doped graphite nanofibers as high durable oxygen reduction catalyst in acidic media for polymer electrolyte fuel cells Adv. Mater. 28 2163-89
  • [29] Fortunelli A(2017)Fluorine-doped and partially oxidized tantalum carbides as nonprecious metal electrocatalysts for methanol oxidation reaction in acidic media J. Colloid Interface Sci. 490 819-79933
  • [30] Chen CY(2015)Hierarchically porous fluorine-doped graphene nanosheets as efficient metal-free electrocatalyst for oxygen reduction in gas diffusion electrode J. Mater. Chem. A 3 9972-4744