N, F-Codoped Microporous Carbon Nanofibers as Efficient Metal-Free Electrocatalysts for ORR

被引:0
作者
Tianle Gong
Ruoyu Qi
Xundao Liu
Hong Li
Yongming Zhang
机构
[1] Shanghai Jiao Tong University,Shanghai Electrochemical Energy Devices Research Center, Shanghai Key Lab of Electrical Insulation and Thermal Aging, School of Chemistry and Chemical Engineering
[2] University of Jinan,School of Material Science and Engineering
来源
Nano-Micro Letters | 2019年 / 11卷
关键词
Metal-free catalyst; Oxygen reduction reaction; N, F-codoped; Carbon nanofiber; Polyvinylidene fluoride;
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学科分类号
摘要
A new and facile method to synthesize N, F-codoped microporous carbon nanofiber (N, F-MCF) electrocatalysts via electrospinning, hydrothermal process, and thermal treatment.Polyvinylidene fluoride is applied as a fluorine source in oxygen reduction reaction (ORR) catalysis for the first time in literature.N, F-MCFs exhibit distinguished electrocatalytic activity, stability, and methanol tolerance for ORR in alkaline media.
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  • [11] Rabis A(2013)Surface and interface control of noble metal nanocrystals for catalytic and electrocatalytic applications Nano Today 8 168-4892
  • [12] Rodriguez P(2015)Metal-free catalysts for oxygen reduction reaction Chem. Rev. 115 4823-372
  • [13] Schmidt TJ(2012)Non precious metal catalysts for the pem fuel cell cathode Int. J. Hydrog. Energy 37 357-365
  • [14] Binninger T(2016)Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts Science 351 361-399
  • [15] Fabbri E(2017)Fe-PPy-TsOH/C as cathode catalyst for proton exchange membrane fuel cells J. Inorg. Mater. 32 393-561
  • [16] Kötz R(2016)Nitrogen-doped carbon foam as a highly durable metal-free electrocatalyst for the oxygen reduction reaction in alkaline solution Electrochim. Acta 220 554-7135
  • [17] Schmidt TJ(2018)Facile synthesis of N-doped graphene-like carbon nanoflakes as efficient and stable electrocatalysts for the oxygen reduction reaction Nano-Micro Lett. 10 29-388
  • [18] Vliet DDF(2018)Creation of triple hierarchical micro–meso–macroporous N-doped carbon shells with hollow cores toward the electrocatalytic oxygen reduction reaction Nano-Micro Lett. 10 3-56
  • [19] Wang DC(2011)Boron-doped carbon nanotubes as metal-free electrocatalysts for the oxygen reduction reaction Angew. Chem. Int. Ed. 50 7132-11668
  • [20] Li D(2018)Identification of electrocatalytic oxygen reduction (ORR) activity of boron in graphene oxide; incorporated as a charge-adsorbate and/or substitutional p-type dopant Mater. Chem. Phys. 207 380-7906