N, F-Codoped Microporous Carbon Nanofibers as Efficient Metal-Free Electrocatalysts for ORR

被引:0
作者
Tianle Gong
Ruoyu Qi
Xundao Liu
Hong Li
Yongming Zhang
机构
[1] Shanghai Jiao Tong University,Shanghai Electrochemical Energy Devices Research Center, Shanghai Key Lab of Electrical Insulation and Thermal Aging, School of Chemistry and Chemical Engineering
[2] University of Jinan,School of Material Science and Engineering
来源
Nano-Micro Letters | 2019年 / 11卷
关键词
Metal-free catalyst; Oxygen reduction reaction; N, F-codoped; Carbon nanofiber; Polyvinylidene fluoride;
D O I
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学科分类号
摘要
A new and facile method to synthesize N, F-codoped microporous carbon nanofiber (N, F-MCF) electrocatalysts via electrospinning, hydrothermal process, and thermal treatment.Polyvinylidene fluoride is applied as a fluorine source in oxygen reduction reaction (ORR) catalysis for the first time in literature.N, F-MCFs exhibit distinguished electrocatalytic activity, stability, and methanol tolerance for ORR in alkaline media.
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  • [1] Wagner FT(2010)Electrochemistry and the future of the automobile J. Phys. Chem. Lett. 1 2204-2219
  • [2] Lakshmanan B(2016)Recent advances in electrocatalysts for oxygen reduction reaction Chem. Rev. 116 3594-7947
  • [3] Mathias MF(2015)Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy ChemInform 43 7933-51
  • [4] Shao M(2012)Electrocatalyst approaches and challenges for automotive fuel cells Nature 486 43-890
  • [5] Chang Q(2012)Electrocatalysis for polymer electrolyte fuel cells: recent achievements and future challenges ACS Catal. 2 864-H128
  • [6] Dodelet JP(2014)Determination of the electrochemically active surface area of metal-oxide supported platinum catalyst J. Electrochem. Soc. 161 H121-3142
  • [7] Chenitz R(2012)Unique electrochemical adsorption properties of pt-skin surfaces & dagger Angew. Chem. Int. Ed. 13 3139-3719
  • [8] Vesborg PCK(2011)Electrocatalysis on platinum nanoparticles: particle size effect on oxygen reduction reaction activity Nano Lett. 11 3714-1419
  • [9] Jaramillo TF(2016)Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction Science 354 1414-456
  • [10] Debe MK(2014)Pt-based nanoarchitecture and catalyst design for fuel cell applications Nano Today 9 433-197