In-plane heterostructured Ag2S-In2S3 atomic layers enabling boosted CO2 photoreduction into CH4

被引:0
作者
Weiwei Shao
Shumin Wang
Juncheng Zhu
Xiaodong Li
Xingchen Jiao
Yang Pan
Yongfu Sun
Yi Xie
机构
[1] University of Science and Technology of China,Hefei National Laboratory for Physical Sciences at Microscale, CAS Centre for Excellence in Nanoscience, National Synchrotron Radiation Laboratory
[2] Hefei Comprehensive National Science Center,Institute of Energy
来源
Nano Research | 2021年 / 14卷
关键词
in-plane heterostructure; atomic layers; carrier dynamics; selective CO; photoreduction;
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中图分类号
学科分类号
摘要
Sluggish separation and migration kinetics of the photogenerated carriers account for the low-efficiency of CO2 photoreduction into CH4. Design and construction two-dimensional (2D) in-plane heterostructures demonstrate to be an appealing approach to address above obstacles. Herein, we fabricate 2D in-plane heterostructured Ag2S-In2S3 atomic layers via an ion-exchange strategy. Photoluminescence spectra, time-resolved photoluminescence spectra, and photoelectrochemical measurements firmly affirm the optimized carrier dynamics of the In2S3 atomic layers after the introduction of in-plane heterostructure. In-situ Fourier transform infrared spectroscopy spectra and density functional theory (DFT) calculations disclose the in-plane heterostructure contributes to CO2 activation and modulates the adsorption strength of CO* intermediates to facilitate the formation of CHO* intermediates, which are further protonated to CH4. In consequence, the in-plane heterostructure achieves the CH4 evolution rate of 20 µmol·g−1·h−1, about 16.7 times higher than that of the In2S3 atomic layers. In short, this work proves construction of in-plane heterostructures as a promising method for obtaining high-efficiency CO2-to-CH4 photoconversion properties.
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页码:4520 / 4527
页数:7
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