Electrochemical reduction of CO2 on Ni (OH)2 doped water dispersible graphene under different electrolyte conditions

被引:0
作者
Siva Palanisamy
Surendhiran Srinivasan
机构
[1] K S Rangasamy College of Technology,Centre for Nano Science and Technology
来源
SN Applied Sciences | 2019年 / 1卷
关键词
CO; Reduction; Carbon dioxide; Electrochemical; Cyclic voltammetry; Linear sweep voltammetry;
D O I
暂无
中图分类号
学科分类号
摘要
Association of the cathodic operation of Ni(OH)2 doped water dispersible graphene (WDG) nanocomposite with three different electrolytes (NaHCO3, KHCO3, and NaCO3) with the help of carbon dioxide (CO2) electrochemical reduction is presented in this research. Graphene in short time is effectively synthesized and Ni(OH)2 doped on WDG by electrochemical method, structure, morphology and characterization analysis by X-ray diffraction, scanning electron microscope, transmission electron microscope and Raman spectroscopy. CO2 is effectively reduced to carbon monoxide (CO) at enhanced situation. Fourier transform infrared spectroscopy, which is used to exanimate integrated Ni(OH)2–WDG nanocomposite surfaces so as to uncover the carbonate ions and CO during reduction at three different electrolytes. The electron charge resistance of the nanocomposite is investigated by using electrochemical impedance spectroscopy analysis. Analysis of the Ni(OH)2–WDG nano composite was performed to decouple electrochemical reduction processes of CO2 to CO at different electrolytes by cyclic voltammetry and linear sweep voltammetry.
引用
收藏
相关论文
共 137 条
  • [1] Gao J(2016)Controllable synthesis of α-MoC Catal Commun 84 147-150
  • [2] Wu Y(2006) and β-Mo Sci Am 295 50-57
  • [3] Jia C(1989)C nanowires for highly selective CO Nature 342 758-761
  • [4] Zhong Z(2010) reduction to CO Clim Dyn 35 1439-1459
  • [5] Gao F(2014)A plan to keep carbon in check Chem Phys Lett 607 5-9
  • [6] Yang Y(2014)Observational determination of the greenhouse effect Am Chem Soc 136 14107-14113
  • [7] Liu B(2010)Reversible and irreversible impacts of greenhouse gas emissions in multi-century projections with the NCAR global coupled carbon cycle-climate model J Phys Chem Lett 1 3451-3458
  • [8] Socolow RH(2013)Atmospheric chemistry of (CF3) 2CFOCH Chem Rev 113 6621-6658
  • [9] Pacala SW(2013)Electrocatalytic conversion of carbon dioxide to methane and methanol on transition metal surfaces Energy Environ Sci 6 3112-3135
  • [10] Raval A(2003)Prospects of CO Appl Electrochem 33 1107-1123