Crystal and molecular structure of tris-(1,1,1-trifluoro-5,5-dimethylhexan-2,4-dionato)iron(III)

被引：0
作者：
I. A. Baidina
N. V. Kurat’eva
P. A. Stabnikov
S. A. Gromilov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Journal of Structural Chemistry | 2007年 / 48卷
关键词：
iron(III) β-diketonates; crystal and molecular structure;
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摘要：
Synthesis and results of the single crystal X-ray diffraction study of iron(III) pivaloyltrifluoroacetonate are reported. Crystal data for C24H30FeF9O6: a = 9.2205(6) Å, b = 9.6584(10) Å, c = 17.3799(17) Å, α = 75.902(2)°, β = 80.517(3)°, γ = 82.746(3)°, space group P-1, V = 1474.6(2) Å3, Z = 2. The structure is molecular with the octahedral environment of Fe atom, Fe-Oav 1.991 Å, ∠O-Fe-Oav 86.48°. The van der Waals energy of intermolecular interactions is calculated and compared to thermodynamic data.
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页码：494 / 499
页数：5
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