Properties of bismuth selenide intercalated with lithium from a solution of n-C4H9Li

被引:0
|
作者
I. I. Grigorchak
V. V. Netyaga
S. V. Gavrilyuk
B. P. Bakhmatyuk
Z. D. Kovalyuk
机构
[1] National Academy of Sciences of Ukraine,Institute of Material Sciences (Chernovtsy Branch)
来源
Physics of the Solid State | 2001年 / 43卷
关键词
Spectroscopy; Lithium; State Physics; Hexane; Bismuth;
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学科分类号
摘要
The lithium-selective intercalation of bismuth selenide (Bi2Se3) samples is accomplished by treating them in a solution of n-butyllithium (n-C4H9Li) in hexane. It is found that, upon incorporation of lithium atoms, the interlayer spacing increases and the resistivity in the direction normal to the layers (ρ⊥) increases by a factor of more than two. The dependence ρ⊥(x) acquires the form of an oscillating function of the degree of guest “load” (the intercalant content) and the frequency-independent portion of the ρ⊥ curve (100 mHz≤ω≤1 MHz) substantially decreases upon completion of the process.
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页码:1442 / 1444
页数:2
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