New volatile complexes of Ni(II) and Pd(II) with 2,2,6,6-tetramethyl-3-amino-4-hepten-5-one: Structure and properties

被引：0

作者：

G. I. Zharkova

I. A. Baidina

P. A. Stabnikov

机构：

[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division

来源：

Journal of Structural Chemistry | 2008年 / 49卷

关键词：

β-iminoketonates; nickel(II); palladium(II); volatility; structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New volatile β-iminoketonate complexes of Ni(L)2 and Pd(L)2 were obtained. β-Aminovinylketone C(CH3)3C(NH2)CHC(O)C(CH3)3 was used as HL. Synthesis of the compound is described, and element analysis, DTA, and IR spectral data are given. The complexes were investigated by XRPA and XRD. The structures are molecular, consist of the trans complexes, and are isostructural. The central atoms have a square plane environment with a (MO2N2) coordination unit. The M-O and M-N distances and the N-M-O valence chelate angles are equal, 1.834 Å, 1.848 Å, and 94.2° for Ni(L)2 and 1.972 Å, 1.975 Å, and 92.4° for Pd(L)2.

引用

页码：309 / 316

页数：7

共 50 条

[21] Synthesis and study of Bimeric Cu(II), Ni(II), Mn(II) and Co(II) Complexes with Schiff base ligands derived from primary aliphatic amines with 3-acetyl-4-hydroxy-6-methyl-5-(phenyldiazenyl)-2H-pyran-2-one
Chandole, S. S.
Pachling, S. P.
Shirodkar, S. G.
RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT, 2010, 14 (02): : 59 - 62
[22] Synthesis, Characterization, and Antibacterial Studies of New Cu(II) and Pd(II) Complexes with 6-Methyl-2-Thiouracil and 6-Propyl-2-Thiouracil
Marinova, Petya
Hristov, Mariyan
Tsoneva, Slava
Burdzhiev, Nikola
Blazheva, Denica
Slavchev, Aleksandar
Varbanova, Evelina
Penchev, Plamen
APPLIED SCIENCES-BASEL, 2023, 13 (24):
[23] Synthesis, characterization and antibacterial activity of some new complexes of Cu(II), Ni(II), VO(II), Mn(II) with Schiff base derived from 4-amino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one
Rosu, Tudor
Pahontu, Elena
Maxim, Catalin
Georgescu, Rodica
Stanica, Nicolae
Almajan, Gabriela Laura
Gulea, Aurelian
POLYHEDRON, 2010, 29 (02) : 757 - 766
[24] Synthesis and multinuclear NMR study of Hg(II), Cd(II), and Pd(II) complexes with biphenylmethylenetriphenylphosphorane: X-ray crystal structure of [{C6H5C6H4CO{(C6H5)3P}CH}HgI2]2
Sabounchei, Seyyed Javad
Gharacheh, Mohsen Ahmadi
Khavasi, Hamid Reza
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (07) : 1165 - 1175
[25] Structure of bis(2-methylimino-3-penten-4-onato) nickel(II). properties of nickel(II) ketoiminates
P. A. Stabnikov
O. S. Koshcheeva
N. V. Pervukhina
G. I. Zharkova
Journal of Structural Chemistry, 2014, 55 : 560 - 563
[26] Spectroscopic, magnetic and thermal properties of new thiocyanato bridged complexes of the type [M(diamine)2]3[Cr(NCS)6]2•nH2O, where M = Cu(II), Ni(II)
Wrzeszcz, G
Dobrzanska, L
POLISH JOURNAL OF CHEMISTRY, 2003, 77 (10) : 1245 - 1254
[27] Synthesis and Characterization of Mono and Mixed Ligand, Ni(II), Pd(II) and Pt(II) Complexes of S-5-Phenyl-1, 3, 4-Oxadiazole-2-yl Benzothioate with some Tertiary Diphosphines Ligands
Saleh, R. A.
Mohammad, H. A.
Gerber, T. I.
Hosten, E. C.
6TH INTERNATIONAL CONFERENCE AND WORKSHOPS ON BASIC AND APPLIES SCIENCES, 2017, 1888
[28] A Dinuclear Ni(II) Complex [Ni2(Htda)2(H2O)6]•4H2O: Synthesis, Crystal Structure and Properties
Zhou Xin-Hui
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (05) : 801 - 806
[29] A new series of Cu(II) and Ni(II) complexes of NO bidentate 4-NO2-benzoylhydrazones: synthesis, characterization, and biological studies
Kucuk, Hatice Baspinar
Kara, Emel Mataraci
Celik, Berna Ozbek
TURKISH JOURNAL OF CHEMISTRY, 2015, 39 (05) : 939 - 954
[30] NEW PD(II) COMPLEXES WITH 4-METHYLAMINO-3-PENTEN-2-ONE CH3C(NHCH3)CHC(O)CH3
Baidina, I. A.
Pervukhina, N. V.
Kryuchkova, N. A.
Gromilov, S. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2025, 66 (01) : 139 - 149

← 1 2 3 4 5 →