Formation and quenching mechanisms of excited particles in an oxygen-iodine laser medium

被引:0
作者
V. N. Azyazov
S. Yu. Pichugin
M. Heaven
机构
[1] Russian Academy of Sciences,Lebedev Physical Institute (Samara Branch)
[2] Emory University,undefined
来源
Optics and Spectroscopy | 2009年 / 107卷
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42.55.Ks;
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摘要
New values of a number of kinetic constants of processes proceeding in oxygen-iodine laser media are presented. The total probabilities of formation of I2(X, 15 ≤ v ≤ 24) and I2(X, 25 ≤ v ≤ 47) molecules in the course of quenching of I* atoms by I2(X) are found to be 0.9 and 0.1, respectively. The quantum yield of singlet oxygen in the reaction O(1D) + N2O → N2 + O2(a1Δ) is close to 100%. The quenching rate constants of I2(A’) by O2, H2O, CO2, I2, and Ar and of I(2P1/2) by O(3P), O3, NO2, N2O4, and N2O are presented.
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页码:363 / 367
页数:4
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