Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol

被引：0
|
作者：
O. V. Ardashov
A. M. Genaev
I. V. Il’ina
D. V. Korchagina
K. P. Volcho
N. F. Salakhutdinov
机构：
[1] Russian Academy of Sciences,Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division
来源：
Russian Journal of Organic Chemistry | 2010年 / 46卷
关键词：
Diol; Potential Energy Surface; Conformational Analysis; Isopropyl Group; Raney Nickel;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Hydrogenation of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol was studied. Nickel chloride-sodium tetrahydridoborate system turned out to selectively reduce the double bond in the isopropenyl group. The results of conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol and its partly and completely hydrogenated derivatives were in a good agreement with the NMR data.
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页码：1786 / 1789
页数：3
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