Palladium(II) and platinum(II) pyrrolate-quinoline-imine chloro-complexes by metal-assisted condensation reactions

被引：0
作者：
Marco Bortoluzzi
Lodovico Agostinis
Valerio Bertolasi
机构：
[1] Università Ca’ Foscari Venezia,Dipartimento di Scienze Molecolari e Nanosistemi
[2] Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC),Dipartimento di Scienze Chimiche e Farmaceutiche e Centro di Strutturistica Diffrattometrica
[3] Università di Ferrara,undefined
来源：
Chemical Papers | 2020年 / 74卷
关键词：
Palladium(II); Platinum(II); -donor ligands; Metal-assisted synthesis;
D O I：
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学科分类号：
摘要：
Neutral palladium(II) and platinum(II) chloro-complexes with the conjugate base of [(pyrrol-2-yl)methylene]quinolin-8-amine were prepared in a single step by reacting 8-aminoquinoline and pyrrole-2-aldehyde with [MCl(CH3)(COD)] (M = Pd, Pt; COD = 1,5-cyclooctadiene). The reaction consists of a metal-assisted condensation and the protonolysis of the M–C bond by the pyrrole NH. The solid-state structure of the palladium derivative was determined by X-ray diffraction, while the electronic features of the complexes were investigated by means of DFT calculations.
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页码：3673 / 3682
页数：9
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