Formation of an α-cyclodextrin/16-mercaptohexadecanoic acid complex and its deposition on gold surfaces

被引：0

作者：

Amanda V. Ellis

Shen Chong

Murray Jansen

机构：

[1] Flinders University,School of Chemistry, Physics and Earth Sciences

[2] Industrial Research Ltd-Nanotechnology Platform,undefined

来源：

Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2009年 / 63卷

关键词：

16-mercaptohexadecanoic acid; -cyclodextrin; H NMR; XRD; XPS;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Using 1H NMR, XRD and XPS techniques we show new findings concerning the nature of the complex formed between 16-mercaptohexadecanoic acid (MHA) and α-cyclodextrin. Stabilization was achieved by dipole-induced dipole interactions between the carboxyl groups of the MHA with the hydroxyls on the cavity rim of the α-cyclodextrin. Deposition of the complex onto a gold substrate with subsequent ethanol washing showed retention of the thiol moiety and removal of cyclodextrin.

引用

页码：267 / 272

页数：5

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