Synthesis and structure of [(nitrito-O,O′) bis(di-2-pyridylamine)copper(II)] nitrite

被引：0
作者：
Alvin A. Holder
Robert T. Stibrany
Nadejda Bolotina
Martin Hall
Vince C.R. Payne
Kristin Kirschbaum
A. Alan Pinkerton
Anthony M. Newton
机构：
[1] Virginia Polytechnic Institute and State University,Department of Chemistry
[2] The State University of New Jersey,Department of Chemistry and Chemical Biology, Rutgers
[3] dCollege of Arts and Sciences,Department of Chemistry
[4] The University of Toledo,Department of Biological and Chemical Sciences
[5] The University of the West Indies,undefined
[6] Cave Hill Campus,undefined
来源：
Journal of Chemical Crystallography | 2004年 / 34卷
关键词：
Nitrite; copper(II); di-2-pyridylamine; hydrogen bonding;
D O I：
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学科分类号：
摘要：
The synthesis and molecular structure of the title compound, [(nitrito-O,O′) (dpa)2Cu(II)] (NO2), 1, is reported. Compound 1 crystallized in the orthorhombic space group Pccn with a = 11.397(5) Å, b = 12.256(6) Å, c = 14.876(8) Å, and V = 2077.9(17) Å3 with Z = 4. The distorted octahedral copper(II) cations are linked through a hydrogen-bonded polymer network. The polymer network is formed through the amine N–H of the cations and hydrogen bonded to the N–H⋅⋅⋅O nitrite anions.
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页码：383 / 386
页数：3
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