Interaction of micas with nickel sulfate solutions

被引：0
|
作者：
V. N. Makarov
I. P. Kremenetskaya
D. V. Makarov
O. P. Korytnaya
T. N. Vasil’eva
机构：
[1] Russian Academy of Sciences,Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resourses, Kola Research Center
来源：
Russian Journal of Inorganic Chemistry | 2008年 / 53卷
关键词：
Sulfate Solution; Nickel Sulfate; Interlayer Cation; Octahedral Layer; Octahedral Cation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The interaction of natural biotites with dilute nickel sulfate solutions at various pHs are studied by X-ray powder diffraction, thermogravimetric analysis, and chemical analysis. K ⇆ Ni, Mg ⇆ Ni, and to a lesser extent Fe ⇆ Ni ion exchange is shown to occur. Nickel can both enter octahedral layers and act as an interlayer cation. Tetrahedral layers have a virtually invariable composition. The mechanoactivation of biotites enhances exchange reactions.
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页码：11 / 21
页数：10
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