Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity

被引：0
作者：
A. V. Mekhaev
A. V. Pestov
P. A. Slepukhin
Yu. G. Yatluk
M. G. Pervova
M. A. Samorukova
O. N. Chupakhin
机构：
[1] Russian Academy of Sciences,Postovskii Institute of Organic Synthesis, Ural Division
来源：
Russian Journal of Organic Chemistry | 2011年 / 47卷
关键词：
Butyl Acrylate; Palladium Complex; Heck Reaction; Iodobenzene; Triazine Ring;
D O I：
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摘要：
Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (SNH reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction.
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页码：1366 / 1369
页数：3
相关论文
共 17 条
  • [1] Heck R.F.(1972)undefined J. Org. Chem. 37 2320-undefined
  • [2] Nolley J.P.(1971)undefined Bull. Chem. Soc. Jpn. 44 581-undefined
  • [3] Mizoroki T.(2000)undefined Chem. Rev. 100 3009-undefined
  • [4] Mori K.(2010)undefined Molecules 15 315-undefined
  • [5] Ozaki A.(1997)undefined J. Heterocycl. Chem. 34 573-undefined
  • [6] Beletskaya I.P.(1995)undefined Acta Crystallogr., Sect. A 51 887-undefined
  • [7] Cheprakov A.V.(2008)undefined Acta Crystallogr., Sect. A 64 112-undefined
  • [8] Huang S.-H.(undefined)undefined undefined undefined undefined-undefined
  • [9] Chen J.-R.(undefined)undefined undefined undefined undefined-undefined
  • [10] Tsai F.-Y.(undefined)undefined undefined undefined undefined-undefined
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