Syntheses, crystal structures, and magnetic properties of three coordination polymers based on manganese(II) and 2,6-naphthalenedicarboxylate

被引：0
作者：
Yaqi Jiang
Rong Yu
Yuelin Bai
Zhaoxiong Xie
Lansun Zheng
机构：
[1] Xiamen University,Department of Chemistry and Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering
来源：
Transition Metal Chemistry | 2008年 / 33卷
关键词：
Phen; Coordination Polymer; Naphthalene Ring; Auxiliary Ligand; Secondary Building Unit;
D O I：
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学科分类号：
摘要：
Three novel coordination polymers, namely, [Mn(ndc)(bpy)]n · n(H2O) (1), [Mn(ndc)(phen)]n (2), and [Mn3(ndc)3(bpy)2]n (3) (H2ndc = 2,6-naphthalenedicarboxylic acid, bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. Complexes 1–3 exhibit three-dimensional metal-organic frameworks (MOFs); 1 and 2 are assemblies of the same secondary building units (SBUs), linear infinite chains {Mn(CO2)2}n, forming one-dimensional channel, while complex 3 is constructed by trinuclear clusters {Mn3(CO2)6} SBUs. Magnetic properties of complexes 1 and 3 are also discussed with respect to the bridging mode of the carboxylate groups.
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页码：1019 / 1026
页数：7
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