Structure and dynamics of liquid water

被引:0
作者
Malenkov G.G. [1 ]
机构
[1] A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow
关键词
Computer simulations; Dynamics; Structure; Water;
D O I
10.1007/s10947-006-0375-8
中图分类号
学科分类号
摘要
A review of recent studies on the structure and dynamics of water (in liquid and amorphous states) by physical methods and computer experiment is presented together with a brief summary of historical background. Basic concepts offered for describing the structure and dynamics of water are considered. The structure of water is currently viewed as having a uniform three-dimensional network formed by hydrogen-bonded molecules. The arrangement of this network is dissimilar from that found in any crystal structures; it is dynamically and structurally inhomogeneous. The network is rather labile; water molecules continuously change their neighbors, so that the average lifetime of hydrogen bonds is about a few picoseconds. © 2006 Springer Science+Business Media, Inc.
引用
收藏
页码:S1 / S31
页数:30
相关论文
共 146 条
[1]  
Malenkov G.G., Structure of Water, Physical Chemistry. Modern Problems, pp. 41-76, (1984)
[2]  
Bernal J.D., Fowler R.H., J. Chem. Phys, 1, pp. 515-548, (1933)
[3]  
Fritzman E.F., Nature of Water. Heavy Water, (1935)
[4]  
Rontgen W.C., Ann. Phys. Chem. N. F, 45, pp. 91-97, (1891)
[5]  
Naberukhin Y.I., Zh. Strukt. Khim, 32, 5, pp. 5-7, (1991)
[6]  
Sinyukov V.V., Structure of Monoatomic Liquids, Water, and Aqueous Solutions of Electrolytes, (1976)
[7]  
Gorbunova K.M., Private communication
[8]  
Pople J.A., Proc. R. Soc, 205, pp. 163-178, (1951)
[9]  
Nemethy G., Scheraga H.A., J. Chem. Phys, 36, pp. 3382-3416, (1962)
[10]  
Samoilov O.Y., Dokl. Akad. Nauk SSSR, 20, pp. 1411-1414, (1946)