Synthesis, Characterization, Thermal Analyses, and Spectroscopic Properties of Novel Naphthyl-Functionalized Imidazolium Ionic Liquids

被引：0
作者：
Meihuan Yao
Qing Li
Yanqiu Xia
Yongmin Liang
机构：
[1] Henan Normal University,School of Chemistry and Chemical Engineering
[2] Lanzhou Institute of Chemical Physics,State Key Laboratory of Solid Lubrication
[3] Chinese Academy of Sciences,School of Energy and Mechanical Engineering
[4] North China Electric Power University,undefined
来源：
Russian Journal of Physical Chemistry A | 2018年 / 92卷
关键词：
ionic liquids; spectroscopy; naphtyl-functionalized; thermal analyses; fluorescence; UV–Vis absorption;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of novel ionic liquids based on naphthyl-functionalized imidazolium cation have been prepared. Their structure was characterized by NMR. The thermal stabilities of the prepared liquids were studied by thermal gravimetric analysis. The new ionic liquids containing NTf-2 anion display significantly higher thermal stabilities (>400°C). Anion exchange to PF-6, BF-4, and Br– decreases the thermal stabilities of such ionic liquids. Fluorescence and UV–Vis absorption spectroscopy were used to study the spectroscopic properties of the ionic liquids. Compared with common ionic liquids, the described ionic liquids provide robust fluorescence properties and remarkably increased UV–Vis absorption. This research may enrich the field of functionalized ionic liquids and provide a platform for extension of ionic liquid applications.
引用
收藏
页码：502 / 507
页数：5
相关论文
共 50 条
  • [21] Synthesis, spectroscopic and molecular docking studies of imidazolium and pyridinium based ionic liquids with HSA as potential antimicrobial agents
    Trush, Maria M.
    Semenyuta, Ivan V.
    Vdovenko, Sergey I.
    Rogalsky, Sergiy P.
    Lobko, Evgeniya O.
    Metelytsia, Larisa O.
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1137 : 692 - 699
  • [22] Syntheses, Crystal Structures, Thermal Properties and Spectroscopic Characterization of Complex Chloridotitanates(IV) with Ionic Liquids
    Leye, Johann-Christian
    Gjikaj, Mimoza
    Adam, Arnold
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (32) : 4837 - 4843
  • [23] Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties
    Karadag, Ahmet
    Akbas, Huseyin
    Karakas, Duran
    Tekin, Kadir Cihan
    Korkmazer, Erdem
    TURKISH JOURNAL OF CHEMISTRY, 2019, 43 (03) : 766 - +
  • [24] Electronic structural properties of amino/hydroxyl functionalized imidazolium-based bromide ionic liquids
    Hu, Xiaoling
    Jia, Xingang
    Su, Kehe
    Gu, Xuefan
    OPEN CHEMISTRY, 2020, 18 (01): : 576 - 583
  • [25] Synthesis and properties of ionic liquids with siloxane-functionalized cations
    E. A. Chernikova
    L. M. Glukhov
    V. G. Krasovskiy
    L. M. Kustov
    A. A. Koroteev
    Russian Chemical Bulletin, 2014, 63 : 2702 - 2706
  • [26] Synthesis and properties of ionic liquids with siloxane-functionalized cations
    Chernikova, E. A.
    Glukhov, L. M.
    Krasovskiy, V. G.
    Kustov, L. M.
    Koroteev, A. A.
    RUSSIAN CHEMICAL BULLETIN, 2014, 63 (12) : 2702 - 2706
  • [27] Synthesis and characterization of novel bronsted acidic ionic liquids
    Wu Qin
    Dong Bin-qi
    Han Ming-han
    Zuo Yi-zan
    Jin Yong
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27 (10) : 2027 - 2031
  • [28] Synthesis and Characterization of 1,2-Dimethyl Imidazolium Ionic Liquids and Their Catalytic Activities
    Ganapathi, Pandurangan
    Ganesan, Kilivelu
    SYNTHETIC COMMUNICATIONS, 2015, 45 (18) : 2135 - 2141
  • [29] Synthesis and Characterization of Epoxy/MCDEA Networks Modified with Imidazolium-Based Ionic Liquids
    Soares, Bluma Guenther
    Livi, Sebastien
    Duchet-Rumeau, Jannick
    Gerard, Jean-Francois
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2011, 296 (09) : 826 - 834
  • [30] Synthesis and characterization of novel ionic liquids based on imidazolium for acid corrosion inhibition of aluminum: Experimental, spectral, and computational study
    El-Saeed, H. M.
    Fouda, A. S.
    Deyab, M. A.
    Shalabi, K.
    Nessim, M. I.
    El-Katori, Emad E.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 358
12345