Synthesis, structure and luminescence studies of heterometallic gold(i)-copper(i) and -silver(i) alkynyl clusters/aggregates

被引：0
作者：
Sung-Kong Yip
Chui-Ling Chan
Wai Han Lam
Kung-Kai Cheung
Vivian Wing-Wah Yam
机构：
[1] The University of Hong Kong,Centre for Carbon
来源：
Photochemical & Photobiological Sciences | 2007年 / 6卷
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摘要：
A series of pentanuclear gold(i)-copper(i) and -silver(i) mixed-metal alkynyl complexes, [nBu4N][Au3M2(C≡CC6H4R-p)6] [M = Cu, R = OMe, OnBu, OnHex, Me, Et; M = Ag, R = Et, OnHex] have been synthesized. The complexes were found to be emissive both in the solid state and in fluid solutions. DFT calculations at the B3LYP level of theory were performed on [Au3M2(C≡CC6H4Me-p)6]− (M = Cu, Ag) to provide an understanding on the electronic structure of the complexes.
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页码：365 / 371
页数：6
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