Two novel interpenetrated zinc(II) and cadmium(II) coordination polymers based on 4-imidazole-benzoate: Syntheses, crystal structures and properties

被引：0
作者：
ZhengShuai Bai
ShuiSheng Chen
ZhengHua Zhang
ManSheng Chen
GuangXiang Liu
WeiYin Sun
机构：
[1] Nanjing University,State Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry, School of Chemistry and Chemical Engineering
来源：
Science in China Series B: Chemistry | 2009年 / 52卷
关键词：
coordination polymer; interpenetration; crystal structure; photoluminescence property;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two novel interpenetrated coordination polymers, [Zn(IBA)2]n (1) and {[Cd(IBA)2(H2O)]·4H2O}n (2), have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal conditions. Complex 1 crystallizes in a chiral space group and has a two-fold interpenetrated 2D network structure with (4,4) topology, while complex 2 is a 3D porous dia network with four nets interpenetrating each other. The SHG activity of 1 and the photoluminescent property of 2 have been investigated.
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页码：459 / 464
页数：5
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共 104 条
[1]  
Eddaoudi M.(2001)Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks Acc Chem Res 34 319-330
[2]  
Moler D. B.(2007)New metal-organic frameworks with large cavities: selective sorption and desorption of solvent molecules Chem Eur J 13 7523-7531
[3]  
Li H. L.(2003)Discrete and infinite cage-like frameworks with inclusion of anionic and neutral species and with interpenetration phenomena Chem Eur J 9 4724-4731
[4]  
Chen B. L.(2003)Reversible anion exchanges between the layered organic-inorganic hybridized architectures: Syntheses and structures of manganese(II) and copper(II) complexes containing novel tripodal ligands Chem Eur J 9 3965-3973
[5]  
Reineke T. M.(2006)Interpenetrating polymer networks for high-performance electroelastomer artificial muscles Adv Mater 18 887-891
[6]  
O’Keeffe M.(2004)A unique 3D alternating ferro- and antiferromagnetic manganese azide system with threefold interpenetrating (10,3) nets Angew Chem Int Ed 43 990-994
[7]  
Yaghi O. M.(2005)Highly interpenetrated metal-organic frameworks for hydrogen storage Angew Chem Int Ed 44 72-75
[8]  
Wang Y.(2004)Interpenetrating metal-organic and inorganic 3D networks: A computer-aided systematic investigation. Part I. Analysis of the cambridge structural database CrystEngComm 6 377-395
[9]  
Huang Y. Q.(1994)Possible hard materials based on interpenetrating diamond-like networks J Am Chem Soc 116 9634-9637
[10]  
Liu G. X.(1997)A packing model for interpenetrated diamondoid structuressan interpretation based on the constructive interference of supramolecular networks Chem Eur J 3 765-771
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