Macrokinetics of Oxidation of Ultradisperse Aluminum by Water in the Liquid Phase

被引：0

作者：

V. G. Ivanov

M. N. Safronov

O. V. Gavrilyuk

机构：

[1] Russian Academy of Sciences,Institute of Petroleum Chemistry, Siberian Division

来源：

Combustion, Explosion and Shock Waves | 2001年 / 37卷

关键词：

Oxidation; Hydrogen; Aluminum; Combustion; Dynamical System;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The processes of oxidation of electroexplosive ultradisperse powders (UDP) of aluminum by water in the range of temperatures 50—75°C are studied by the method of continuous recording of gas release. It is shown that the electroexplosive UDP of aluminum are capable to be actively oxidized by water with the formation of oxide—hydroxide phases and hydrogen release already upon moderate heating. At temperatures higher than 75°C the oxidation occurs like a degenerate thermal explosion. The macrokinetic parameters of the oxidation of aluminum UDP are determined. The data obtained can be used to assess the fire hazard of UDP in the presence of moisture and analyze the combustion of aluminum UDP in the composition of energy materials.

引用

页码：173 / 177

页数：4

共 13 条

[1]

Morokhov I. D.(1983)Structure and properties of fine particles Usp. Fiz. Nauk 133 653-692

[2]

Petinov V. I.(1990)Specific features of the interaction of submicron aluminum powders with liquid water: Macrokinetics, products, and manifestation of self-heating Kinet. Katal. 31 967-972

[3]

Trusov L. I.(1994)Combustion of mixtures of ultradisperse aluminum with gellike water Fiz. Goreniya Vzryva 30 167-168

[4]

Petrunin V. F.(1997)Application of new adsorbents to complex purification of water Khim. Interes. Ust. Razv. 5 429-437

[5]

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