Phase transitions and ion transport in NASICON materials of composition Li1 + xZr2 − xInx(PO4)3(x = 0–1)

被引：0

作者：

D. V. Safronov

I. A. Stenina

A. V. Maksimychev

S. L. Shestakov

A. B. Yaroslavtsev

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

[2] Russian Academy of Sciences,Higher Chemical College

[3] Moscow Physicotechnical Institute,undefined

来源：

Russian Journal of Inorganic Chemistry | 2009年 / 54卷

关键词：

Doping Level; Solid State Ionic; Magic Angle Spin; Rhombohedral Phase; Zirconium Phosphate;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

NASICON materials of composition Li1 + xZr2 − xInx(PO4)3(x = 0–1) were synthesized. The phase constitution, particle size, and conductivity of these materials were studied as s function of synthesis temperature. High-temperature X-ray powder diffraction was used to study phase transitions in the materials synthesized. Low levels (x ≤ 0.1) partial substitution of indium for zirconium considerably increase the lithium ion conductivity and reduce the activation energy for conduction compared to the parent compound.

引用

页码：1697 / 1703

页数：6

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