Spectroscopy and X-ray studies of {{6,6′-dimethoxy-2,2′-[ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate

被引：0
作者：
Ç Yüksektepe Ataol
N. Şenyüz
H. Bat
机构：
[1] Cankiri Karatekin University,Department of Physics, Faculty of Science
[2] Ondokuz Mayis University,Department of Chemistry, Faculty of Arts and Sciences
来源：
Russian Journal of Coordination Chemistry | 2014年 / 40卷
关键词：
Schiff Base; Bipy; Dimethoxy; Molecular Hydrogen Bond; Dioxouranium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The C18H20N2O7U · 2H2O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) Å, V = 4252(3) Å3 and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds.
引用
收藏
页码：671 / 675
页数：4
相关论文
共 18 条
  • [1] Şenyüz N(2006)undefined Acta Crystallogr., Sect. E: Structure Reports Online 62 m3163-undefined
  • [2] Yüksektepe C(2002)undefined Polyhedron 21 2547-undefined
  • [3] Batı H(1995)undefined Coord. Chem. Rev. 139 17-undefined
  • [4] Tarafder MTH(1992)undefined React. Kinet. Catal. Lett. 48 575-undefined
  • [5] Jin KT(1995)undefined Polyhedron 14 1221-undefined
  • [6] Crouse KA(1972)undefined Chem. Rev. 72 203-undefined
  • [7] Guerriero P(1997)undefined J. Appl. Crystllogr. 30 565-undefined
  • [8] Tamburini S(2005)undefined Acta. Crystallogr., Sect. C: Cryst. Struct. Commun. 61 m482-undefined
  • [9] Vigato PA(undefined)undefined undefined undefined undefined-undefined
  • [10] Sreekala R(undefined)undefined undefined undefined undefined-undefined
12