Thermal transformations of complexes Co2(μ-OOCBut)4(NEt3)2 and Co3(μ-OOCBut)2(μ-OOCBut)4(NEt3)2

被引:0
作者
S. E. Nefedov
T. O. Denisova
Zh. B. Dobrokhotova
F. M. Dolgushin
G. V. Romanenko
V. N. Ikorskii
V. I. Ovcharenko
机构
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Chemistry
[3] Russian Academy of Sciences,International Tomography Center, Siberian Division
来源
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词
Differential Scanning Calorimetry; Thermolysis; Effective Magnetic Moment; Thermal Transformation; Pivalic Acid;
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学科分类号
摘要
The features of thermal transformations of trimethylacetatocobalt complexes Co2(μ-OOCBut)4(NEt3)2 and Co3(μ-OOCBut)2(μ-OOCBut)4(NEt3)2 with attendant geometric alterations are considered as dependent on temperature on the basis of single-crystal X-ray diffraction, magnetochemical, and thermochemical investigations.
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页码:1587 / 1601
页数:14
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