Group transfer polymerization of acrylonitrile in bulk at ambient temperature

被引:0
|
作者
Junsong Zhang
Mincan Wang
Jianhai Wang
Yanyan Shi
Jingchao Tao
Dekun Wang
机构
[1] Zhengzhou University,Department of Chemistry
来源
Polymer Bulletin | 2005年 / 54卷
关键词
Polymerization; Molecular Weight; Ambient Temperature; Good Yield; Acrylonitrile;
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暂无
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学科分类号
摘要
Group transfer polymerization of acrylonitrile was conducted in bulk at room temperature with 1,1,3-trimethyl-5-methylen-2, 6-dioxa-1-silacyclohexen (TMDSCH) as the initiator and tetrabutylammonium bibenzoate (TBABB) as the catalyst. The experimental results showed that the new GTP initiator gave polyacrylonitrile in fairly good yields with well control of the molecular weight and polydispersity.
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页码:157 / 161
页数:4
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