Thermodynamic Properties of Metal-Carbon Melts

被引:0
作者
V. G. Kudin
V. A. Makara
机构
[1] Shevchenko National University,
来源
Inorganic Materials | 2005年 / 41卷
关键词
Experimental Data; Carbide; Enthalpy; Inorganic Chemistry; Calorimetry;
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中图分类号
学科分类号
摘要
The partial and total enthalpies of mixing of Si-C and Ni-C liquid alloys at 2000 K are determined by isoperibol calorimetry. The mixing enthalpies in these systems are found to be small and negative, in agreement with earlier results. The thermochemical properties of dilute Al-C solutions are studied at 1773 K for the first time. The mixing enthalpies of metal-carbon melts are estimated from the standard enthalpies of formation of metal carbides. The calculated mixing enthalpies of liquid metal-carbon alloys agree with experimental data.
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页码:591 / 594
页数:3
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