Calculation of the molecular-mass distribution for hyperbranched macromolecules synthesized by living three-dimensional radical polymerization

被引：0
|
作者：
S. A. Kurochkin
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Polymer Science Series B | 2010年 / 52卷
关键词：
Polymer Science Series; Hyperbranched Polymer; Molecular Mass Distribution; Monovinyl; Critical Conversion;
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摘要：
Kinetic analysis of the scheme underlying the formation of branched and hyperbranched macro- molecules formed by living three-dimensional radical po lymerization in the pregel period makes it possible to derive some theoretical dependences relating the conditions of polymerization and the molecular-mass distribution of polymers. In this case, a polymer product constitutes a mixture of macromolecules with different degrees of branching, and the fractional weight of macromolecules with hyperbranched structure is no more than one-third with respect to the overall polymer product.
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页码：109 / 117
页数：8
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