Construction of a new one-dimensional Hg(II) coordination polymer [Hg4(Chbz)4(4,4′-Bipy)2(NO3)4 · H2O]n involving in situ chlorobenzene synthesis

被引：0
作者：
J. M. Zhou
X. C. Niu
机构：
[1] Guangdong University of Petrochemical Technology,College of Chemistry and Life Science
[2] Guangdong University of Petrochemical Technology,College of Chemical and Environmental Engineering
来源：
Russian Journal of Coordination Chemistry | 2013年 / 39卷
关键词：
Coordination Polymer; Bipy; Thermal Gravimetric Analysis; Free Water Molecule; Mercury Salt;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new 1D Hg(II) coordination polymer, [Hg4(Chbz)4(4,4′-Bipy)2(NO3)4 · H2O]n (I) (Chbz = 2-chlorophenyl, 4,4′-Bipy = 4,4′-bipyridine), has been synthesized by the in situ synthesis of 2-chlorophenyl from the reaction of 2-chlorobenzoic acid, 4,4′-Bipy and mercury salt under hydrothermal conditions and characterized by elemental analysis, IR, TGA and single-crystal X-ray diffraction. Complex I exhibits an interesting 1D infinite zigzag polymeric chain along the x axis. The photoluminescent measurements reveal that complex I exhibits fluorescent emission in the solid state at room temperature.
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页码：388 / 392
页数：4
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