Synthesis, IR spectra, and solid-state luminescence of triphenylguanidinium salts with the anions B10H102−, B12H122−, B9C2H122−, [Co(C2B9H11)2]−, and [Ni(C2B9H11)2]−

被引：0
作者：
E. A. Il’inchik
M. K. Drozdova
O. P. Yur’eva
K. G. Myakishev
V. V. Volkov
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
None None; Cesium Salt; Boron Hydride; Sample Luminescence; Local Hydrogen Bond;
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学科分类号：
摘要：
Triphenylguanidinium Ph3GH+ salts with the anions B10H102−, B12H122−, B9C2H122−, [Co(C2B9H11)2]−, and [Ni(C2B9H11)2]− were synthesized and described by DTA, IR spectroscopy, and solid-state luminescence. By IR spectroscopy, it was shown that intermolecular interactions involving the NH groups of the cation are enhanced in the sequence [Co(C2B9H11)2]− ∼ [Ni(C2B9H11)2]− < B9C2H122− < B12H122− < B10H102−.
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页码：1866 / 1871
页数：5
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