New tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment: Synthesis, optical properties, and electrochemical behavior

被引：0
作者：
E. A. Ignatenko
E. V. Shklyaeva
G. G. Abashev
机构：
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
[2] Perm State National Research University,Institute of Natural Sciences
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
Pyrrole; Thiophene; Tetrathiafulvalenes; Methylsulfanyl; Triethyl Phosphite;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of 1-(3-bromopropyl)-2,5-bis(thiophen-2-yl)-1H-pyrrole with cesium 5-methylsulfanyl-2-thioxo-1,3-dithiole-4-thiolate generated in situ gave previously unknown 4-{3-[2,5-bis(thiophen-2-yl)-1H-pyrrol-1-yl]propylsulfanyl}-5-methylsulfanyl-1,3-dithiole-2-thione, and cross-coupling of the latter with 4,5-disubstituted 1,3-dithiole-2-thiones in the presence of triethyl phosphite afforded new substituted tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment. Optical properties and electrochemical behavior of the synthesized compounds were studied, and their ability to undergo electropolymerization was confirmed.
引用
收藏
页码：1379 / 1385
页数：6
相关论文
共 76 条
  • [1] Bryce MR(2000)undefined J. Mater. Chem. 10 589-undefined
  • [2] Syutkin R(2007)undefined Butlerov. Soobshch. 11 63-undefined
  • [3] Abashev G(2011)undefined Russ. J. Org. Chem. 47 530-undefined
  • [4] Shklyaeva E(1998)undefined Adv. Mater. 10 541-undefined
  • [5] Syutkin RV(2004)undefined J. Phys. IV. France 114 493-undefined
  • [6] Abashev GG(2006)undefined Russ. J. Org. Chem. 42 1873-undefined
  • [7] Shklyaeva EV(2007)undefined Russ. J. Org. Chem. 43 135-undefined
  • [8] Kudryavtsev PG(2007)undefined Butlerov. Soobshch. 12 10-undefined
  • [9] Huchet L(2008)undefined Solid State Sci. 10 1710-undefined
  • [10] Akoudad S(2003)undefined J. Mater. Chem. 13 1011-undefined
12345678