Na(H2O)[Mn(H2O)2(BP2O8)]: Crystal structure refinement

被引：0
|
作者：
O. V. Yakubovich
I. Steele
O. V. Dimitrova
机构：
[1] Moscow State University,Faculty of Geology
[2] University of Chicago,undefined
来源：
Crystallography Reports | 2009年 / 54卷
关键词：
61.10.Nz;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal structure of synthetic manganese sodium borophosphate hydrate Na(H2O)[Mn(H2O)2(BP2O8)] was refined based on X-ray diffraction data. The compound was prepared by soft hydrothermal synthesis in the MnCl2-Na3PO4-B2O3-H2O system. The unit-cell parameters are a= 9.602(1) Å, c= 16.037(3) Å, sp. gr. P6522, Z= 6, Dx = 2.57 g/cm3. The water molecules were found to be statistically distributed in the channels of the mixed anionic paraframework consisting of (BO4) and (PO4) tetrahedra and [MnO4(H2O)2] octahedra. The hydrogen atoms of the water molecules coordinated to the Mn2+ cations were located and their positional and thermal parameters were refined. The crystal-chemical features of borophosphates of the general formula AxM(H2O)2(BP2O8)(H2O) are considered.
引用
收藏
页码：13 / 18
页数：5
相关论文
共 50 条
  • [1] Na(H2O)[Mn(H2O)2(BP2O8)]: Crystal structure refinement
    Yakubovich, O. V.
    Steele, I.
    Dimitrova, O. V.
    CRYSTALLOGRAPHY REPORTS, 2009, 54 (01) : 13 - 18
  • [2] Synthesis and Crystal Structure of SrFe [BP2O8(OH)2] and CaCo(H2O)[BP2O8(OH)] •H2O
    Menezes, Prashanth Wilfred
    Hoffmann, Stefan
    Prots, Yurii
    Kniep, Ruediger
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2009, 65 : S181 - S181
  • [3] Synthesis and Crystal Structure of CaCo(H2O)[BP2O8(OH)] • H2O
    Menezes, Prashanth W.
    Hoffmann, Stefan
    Prots, Yurii
    Kniep, Ruediger
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (4-5): : 614 - 617
  • [4] Crystal structure of potassium diaquamanganese(II) borophosphate monohydrate, K[Mn(H2O)2(BP2O8)] • H2O
    Wang, Ming-Zhen
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (01): : 3 - 4
  • [5] Crystal structure and thermochemical properties of a first scandium borophosphate, Sc(H2O)2[BP2O8]•H2O
    Ewald, B
    Prots, Y
    Kudla, C
    Grüner, D
    Cardoso-Gil, R
    Kniep, R
    CHEMISTRY OF MATERIALS, 2006, 18 (03) : 673 - 679
  • [6] X-ray powder diffraction and IR study of NaMg(H2O)2[BP2O8]•H2O and NH4Mg(H2O)2[BP2O8]•H2O
    Baykal, A
    Kizilyalli, M
    Kniep, R
    JOURNAL OF MATERIALS SCIENCE, 2000, 35 (18) : 4621 - 4626
  • [7] X-ray powder diffraction and IR study of NaMg(H2O)2[BP2O8]·H2O and NH4Mg(H2O)2[BP2O8]·H2O
    A. Baykal
    M. Kizilyalli
    R. Kniep
    Journal of Materials Science, 2000, 35 : 4621 - 4626
  • [8] Crystal structure of lithium cadmium diaqua catena-[monoborodiphosphate]-monohydrate, LiCd(H2O)2[BP2O8] • H2O
    Ge, MH
    Mi, JX
    Huang, YX
    Zhao, JT
    Kniep, R
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (03): : 273 - 274
  • [9] Crystal structure of diaqua-indium catena-monoboro-bisphosphate monohydrate, In(H2O)2[BP2O8] • H2O
    Ewald, B
    Prots, Y
    Menezes, P
    Kniep, R
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (04): : 351 - 352
  • [10] Synthesis, Crystal Structure and Characterization of a new Protonated Magnesium Borophosphate: (H3O)Mg(H2O)2[BP2O8]•H2O
    Yang, Yang
    Wu, Jian
    Wang, Yu
    Zhu, Jiang
    Liu, Ruibin
    Meng, Changgong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (01): : 137 - 141
12345