Solubility of argon and nitrogen in aqueous solutions of tetradecyltrimethylammonium bromide from 283.15 to 298.15 K and 101,325 Pa partial pressure of gas

被引:0
作者
Luis C. A. Garzon
Andres F. Suarez
Carmen M. Romero
机构
[1] Universidad Nacional de Colombia,Departamento de Química, Facultad de Ciencias
[2] Universidad de Bogotá Jorge Tadeo Lozano,Facultad de Ciencias Naturales e Ingeniería
来源
Journal of Thermal Analysis and Calorimetry | 2017年 / 128卷
关键词
Gas solubility; Aqueous solution; Tetradecyltrimethylammonium bromide; Surfactants; Micelles;
D O I
暂无
中图分类号
学科分类号
摘要
This paper reports experimental results regarding the solubility of argon and nitrogen in aqueous solutions of tetradecyltrimethylammonium bromide (TTAB) at temperatures between 283.15 and 298.15 K, 101,325 Pa partial pressure of gas, and 0.04–0.20 mol kg−1 of TTAB concentration. Measurements were taken in specially developed equipment, following the change in gas pressure. The gas solubility was determined applying Henry’s law. The experimental results show that the solubility of argon and nitrogen in the TTAB micelles is 62.5–86.3 times higher than the solubility in pure water. The solubility of the studied gases is larger in the TTAB micelles than in the DTAB determined in a previous work under the same experimental conditions, showing the effect of the addition of a methylene group in the alkyl chain of DTAB. Comparing the results obtained, it can be observed that the TTAB micelles are larger and have a higher solubilization capacity.
引用
收藏
页码:475 / 479
页数:4
相关论文
共 66 条
  • [1] Battino R(1966)The solubility of gases in liquids Chem Rev 66 395-463
  • [2] Clever HL(2011)The O J Chem Eng Data 56 5036-5044
  • [3] Battino R(2008)/N J Electroanal Chem 617 157-163
  • [4] Seybold PG(2011) ratio gas solubility mystery J Chem Eng Data 56 727-732
  • [5] Raposo RR(2004)A new electrochemical method for the determination of gas solubility in aqueous solutions Mar Geol 203 177-184
  • [6] Calviño E(1997)Correlations involving the solubility of gases in water at 298.15 K and 101325 Pa J Colloid Interface Sci 196 53-61
  • [7] Esteso MA(2007)Ethane solubility in marine hydrate environments J Colloid Interface Sci 309 505-510
  • [8] Battino R(1995)Prediction of solubility of nonpolar gases in micellar solutions of ionic surfactants Adv Colloid Interface Sci 58 171-209
  • [9] Seybold PG(2008)The solubility of ethane in aqueous solutions of sodium 1-pentanesulfonate, sodium 1-hexanesulfonate, sodium 1-heptanesulfonate, and sodium 1-octanesulfonate at 25 °C Langmuir 24 10771-10775
  • [10] Campanell FC(1983)Thermodynamics of micellar systems: comparison of mass action and phase equilibrium models for the calculation of standard Gibbs energies of micelle formation J Solut Chem 12 861-868