[3+2] Cycloaddition reactions of 1-substituted 3,3,3-trifluoropropenes with isonitriles – synthesis of pyrroles and pyrrolines

被引：0

作者：

Yuriy N. Markitanov

Vadim M. Timoshenko

Eduard B. Rusanov

Yuriy G. Shermolovich

机构：

[1] Institute of Organic Chemistry,

[2] National Academy of Sciences of Ukraine,undefined

来源：

Chemistry of Heterocyclic Compounds | 2021年 / 57卷

关键词：

ethyl isocyanoacetate; pyrrole; pyrrolidine; pyrroline; sulfamide; sulfone; sulfoximine; tosylmethyl isocyanide; trifluoromethyl group; cycloaddition;

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暂无

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摘要：

Cycloaddition reactions of 3,3,3-trifluoropropene derivatives containing an alkoxycarbonyl, sulfonyl, sulfoximine, or sulfamide substituent in position 1 with ethyl isocyanoacetate proceed with the formation of 3-(trifluoromethyl)-2,3-dihydro-1H-pyrroles, whereas their reactions with tosylmethyl isocyanide lead to the formation of 4-(trifluoromethyl)-1H-pyrroles.

引用

页码：253 / 260

页数：7